The unique relationship between the compressibility factor and the reduced temperature,, and the reduced pressure,, was first recognized by van der Waals in 1873 and is known as the two parameter principle of corresponding states. The principle of corresponding states expresses the generalization that the properties of a gas which are dependent on intermolecular forces are related to the critical properties of the gas in a universal way. That provides a most important basis for developing correlations of molecular properties..
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